Defined term · Analytical chemistry
Mass spectrometry
Determination of mass-to-charge ratio, used to confirm identity. For a peptide, deconvolution of the multiply charged envelope should return an average mass within a stated tolerance of the…
§1Mass spectrometry
§1.1Also known as
MS ESI-MS
§1.2Category
Analytical chemistry — Terms describing the determination of identity, purity, content and quality.
§1.3Related terms
- Monoisotopic mass — The mass calculated using the most abundant isotope of each element. Requires high resolving power to determine for a peptide of several kilodaltons, and is not…
- Orthogonal method — A second analytical method resting on a different physical principle from the first. Identity confirmed by two orthogonal methods is materially stronger than identity…
Compound Evidence Institute · CEI-GT-142 · https://compoundevidence.com/glossary/mass-spectrometry/ · retrieved 30 July 2026